Billy Bob Thornton
Particularly, the top one in list Hollywood stars with multiple divorces is a Billy Bob Thornton. As known for his role in Fargo, has had a tumultuous marital history, having been married six times and divorced five times. His first marriage was to Melissa Lee Gatlin in 1978, followed by marriages to Toni Lawrence, Cynda Williams, and Pietra Thornton over the next two decades.
In 2000, Thornton made headlines when he married Angelina Jolie, a union that began while he was still engaged to actress Laura Dern. Dern famously commented in an interview with Talk magazine, revealing that her boyfriend had married someone else while she was away, and she never heard from him again. Despite the initial attention, Thornton and Jolie's marriage ended a few years later. In 2014, Thornton married Connie Angland, marking his sixth marriage.